| 王倩楠,顾春平,孙伟.水泥-粉煤灰-硅灰基超高性能混凝土水化过程微观结构的演变规律[J].材料导报,2017,31(23):85-89 |
| 水泥-粉煤灰-硅灰基超高性能混凝土水化过程微观结构的演变规律 |
| Microstructure Evolution During Hydration Process of Ultra-High Performance Concrete Containing Fly Ash and Silica Fume |
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| DOI：10.11896/j.issn.1005-023X.2017.023.011 |
| 中文关键词: 超高性能混凝土(UHPC) 浆体 反应程度 氢氧化钙 孔结构 水化过程 |
| 英文关键词: ultra-high performance concrete (UHPC), paste, reaction degree, calcium hydroxide, pore structure, hydration process |
| 基金项目:国家重点基础研究发展计划(973计划) (2009CB623200)； 国家自然科学基金青年科学基金(51708502) |
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| 中文摘要: |
| 超高性能混凝土(UHPC)具有卓越的力学性能和耐久性能,应用前景广阔。采用扫描电镜背散射电子图像、热重法和氮气吸附法系统研究了水泥-粉煤灰-硅灰基UHPC浆体水化过程中微观结构的演变过程。结果表明:UHPC浆体在早期水泥水化较快,但7 d后水化变得较为缓慢,粉煤灰在UHPC浆体中反应较为缓慢,28 d时反应程度仅为7%；UHPC浆体中Ca(OH)2含量早期上升快速,由于硅灰和粉煤灰的火山灰反应逐渐消耗,3 d后含量开始下降,但28 d时浆体中仍存在部分Ca(OH)2；此外,在水化过程中,UHPC浆体的比表面积不断降低,孔隙率逐渐下降,水化产物变得更为致密。 |
| 英文摘要: |
| Ultra-high performance concrete (UHPC) is a promising material which exhibits extrodinary mechanical properties and durability. A UHPC paste containing fly ash and silica fume was prepared and its microstructure evolution during hydration was investigated with backscattered electron (BSE) images, thermogravimetry (TG) and nitrogen adsorption method. The results showed that the hydration of cement was fast at early ages, and it slowed down after 7 days. Due to its low activity, fly ash reacted slowly in the paste. The reaction degree of fly ash was only 7% by 28 days. The content of Ca(OH)2 increased quickly at first as the cement hydrated. After 3 days it started to decline due to the consumption by pozzolanic reactions of silica fume and fly ash. There was still some Ca(OH)2 existing in the paste by 28 days. Moreover, the specific surface area and the porosity of UHPC paste decreased as the curing progressed, resulting in a denser microstructure. |
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